Template Synthesis of Hierarchical Bi2E3 (E ) S, Se, Te) Core-Shell Microspheres and Their Electrochemical and Photoresponsive Properties
نویسندگان
چکیده
Hierarchical, core-shell structured microspheres of bismuth chalcogenides (Bi2E3, E ) S, Se, Te) have been synthesized by chemical transformation of reactive precursor templates, which involves the formation of intermediate BiOCl mircrospheres and their subsequent hydrothermal transformation into Bi2E3 core-shell microspheres. The uniform precursor microspheres consisting of BiOCl nanoplates were obtained by the hydrolysis of BiCl3 under the direction of dextran sulfate. It was proposed that the core-shell structured Bi2E3 microspheres were produced by the chemical transformation of the BiOCl microspheres through the microscale Kirkendall effect. It was found that the obtained core-shell Bi2S3 microspheres could electrochemically charge and discharge with a capacity of 110 mA h g-1 at room temperature. Furthermore, the photoresponsive properties of the hierarchical Bi2S3 core-shell microspheres were investigated, which showed better sensitivity than normal Bi2S3 nanorods, probably owing to multiple reflections of light within the sphere interior voids, indicating their potential applications in photodetectors and photoelectronic switches.
منابع مشابه
Acetone sensing properties of hierarchical WO3 core-shell microspheres in comparison with commercial nanoparticles
In this work, hierarchical WO3 core-shell microspheres were synthesized via a facile template-free precipitation method. Gas sensing properties of the synthesized powder to acetone and some other volatile organic compounds were comparatively investigated with commercial WO3 nanoparticles. The synthesized and commercial powders were characterized by X-ray diffraction, scanning electron microscop...
متن کاملAcetone sensing properties of hierarchical WO3 core-shell microspheres in comparison with commercial nanoparticles
In this work, hierarchical WO3 core-shell microspheres were synthesized via a facile template-free precipitation method. Gas sensing properties of the synthesized powder to acetone and some other volatile organic compounds were comparatively investigated with commercial WO3 nanoparticles. The synthesized and commercial powders were characterized by X-ray diffraction, scanning electron microscop...
متن کاملSurfactant Removal from Mesoporous Silica Shell of Core-Shell Magnetic Microspheres by Modified Supercritical CO2
In this paper, a kind of core–shell magnetic mesoporous microspheres of Fe3O4@SiO2@meso-SiO2 with high surface areawas prepared, where magnetic Fe3O4 nanospheres were used as the inner core, tetraethyl orthosilicate (TEOS) as silica source, and cetyltrimethylamonium bromide (CTAB) as pore forming agent. Methanol-enhanced s...
متن کاملFacile and Efficient Self-template Synthesis of Core-coronal-shell ZnO@ZIF-8 Nanohybrid Using Ascorbic Acid and its Application for Arsenic Removal
In the present contribution, a facile and efficient protocol for synthesis a nanohybrid structure of core-coronal-shell ZnO@ZIF-8 using ascorbic acid (ZnO@AA/ZIF-8) as a new adsorbent for arsenic removal from water has been represented. For this purpose, the ZnO nanospheres were synthesized by a green and simple method followed by coating with ascorbic acid (AA) to modify their surface to achie...
متن کاملCore-shell nanoparticles for medical applications: effects of surfactant concentration on the characteristics and magnetic properties of magnetite-silica nanoparticles
Objective(s): The use of cationic surface-active agents (surfactant) in the synthesis of nanoparticles, with formation of micelle, can act as a template for the formation of meso-porous silica. Changes in the concentration of surfactants can affect the structures and properties of the resulting nanoparticles.Materials and Methods: Magnetite nanoparticles were prepared as cores using the c...
متن کامل